By James J Spivey; Yi-Fan Han; K M Dooley
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An figuring out of statistical thermodynamic molecular concept is key to the appreciation of molecular strategies. This complicated topic has been simplified by means of the authors with down-to-earth shows of molecular concept. utilizing the aptitude distribution theorem (PDT) because the foundation, the textual content presents an updated dialogue of useful theories along side simulation effects.
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Extra resources for Catalysis, Volume 25
The slow-down of the CO* and H* oxidation reactions makes desorption of syngas competitive with its combustion. As a result, syngas is produced via a ‘‘direct route’’, since H2O adsorption is not needed. In this second zone, a mixed mode with competition between the direct path of methane to syngas and syngas combustion is found. The lack of excess adsorbed oxygen activates the pyrolytic chemistry over the oxidative chemistry. 61 An additional key observation of the model analysis is that the main oxidizer is OH* rather than O*.
Panel c: measured and simulated O2 concentration proﬁle. Adapted from Applied Catalysis A: General, Volume 402, A. Donazzi, D. Livio, A. Beretta, G. Groppi and P. Forzatti, Surface temperature proﬁles in CH4 CPO over honeycomb supported Rh catalyst probed with in situ optical pyrometer, 41–49, Copyright (2011), with permission from Elsevier. 1039/9781849737203-00001 View Online the simulations of our predictive numerical model (panel b), a very close match was found and the adequacy of the pyrometer measurements with 451 angled ﬁbers was veriﬁed.
This has been recently achieved by inserting suitable probes inside the insulated reactor, as illustrated in the following paragraph. 1039/9781849737203-00001 View Online Fig. 13 Reactor set-up for spatially resolved sampling technique. Adapted from: Catalysis Letters, 110, 2006, 169–178, Spatial and temporal proﬁles in millisecond partial oxidation processes, R. Horn, N. J. Degenstein, K. A. Williams and L. D. Schmidt, Fig. 1, original copyright notice, with kind permission from Springer Science and Business Media.